Solubility of erythromycin in ionic liquids

Manic, Marina S. and Najdanovic, Vesna (2012) Solubility of erythromycin in ionic liquids. Journal of Chemical Thermodynamics, 44 (1). pp. 102-106. ISSN 0021-9614

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Abstract

(Solid + liquid) and (liquid + liquid) phase equilibria of binary mixtures containing various ionic liquid and erythromycin were studied. The solubility of erythromycin in 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, or 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, or trihexiltertadecilphosphonium chloride, or butyltrimethylammonium bis(trifluoromethylsulfonyl)imide, or methyltrioctylammonium bis(trifluoromethylsulfonyl)imide, or 1-butyl-1 -methyl-pyrrolidinium bis(trifluoromethylsulfonyl)imide has been measured by a dynamic method, in a wide range of temperatures from (284 to 358) K, at atmospheric pressure. The activity coefficients of erythromycin in ionic liquids were calculated and their comparison with ideal solution was discussed. The experimental data were correlated successfully by means of the semi-empirical Grant equation.

Item Type:
Journal Article
Journal or Publication Title:
Journal of Chemical Thermodynamics
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2500
Subjects:
?? solventswateractivity coefficientssolubilitya dihydrate2-phase system(solid plus liquid) equilibriaextractionantibioticgeneral materials scienceatomic and molecular physics, and opticsphysical and theoretical chemistrymaterials science(all) ??
ID Code:
62331
Deposited By:
Deposited On:
13 Feb 2013 14:46
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 09:17