Photocatalysed degradation of a herbicide derivative, Dinoterb, in aqueous suspension

Dar, A. A. and Umar, K. and Mir, N. A. and Haque, M. M. and Muneer, M. and Boxall, C. (2011) Photocatalysed degradation of a herbicide derivative, Dinoterb, in aqueous suspension. Research on Chemical Intermediates, 37 (6). pp. 567-578. ISSN 0922-6168

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Abstract

The photocatalytic degradation of a herbicide derivative, Dinoterb (1), has been investigated in aqueous micellar solution in the presence of titanium dioxide (TiO2) and air as a function of irradiation time under a variety of conditions using UV and HPLC analysis techniques. The degradation kinetics was studied under different conditions such as different types of TiO2, catalyst concentration, substrate concentration and reaction pH in the presence of air. The photocatalyst Degussa P25 was found to be more efficient catalyst as compared to other photocatalysts tested. The model compound was found to degrade more efficiently under neutral pH as compared to acidic and alkaline pH. GC/MS analysis of the irradiated samples indicate the formation of 2-isopropyl-4,6-dinitro-phenol as by-product which has been characterized on the basis of molecular ion and mass fragmentation pattern. A probable pathway for its formation has been proposed.

Item Type:
Journal Article
Journal or Publication Title:
Research on Chemical Intermediates
Uncontrolled Keywords:
/dk/atira/pure/researchoutput/libraryofcongress/ta
Subjects:
ID Code:
50490
Deposited By:
Deposited On:
26 Oct 2011 12:43
Refereed?:
Yes
Published?:
Published
Last Modified:
17 Jun 2020 01:48