Overview of the latest progress and prospects in the catalytic hydrogenation of carbon dioxide (CO2) to methanol in membrane reactors

Mohammed, Mustapha Grema and Hashim, N. Awanis and Daud, Wan Mohd Ashri Wan and Hartley, Unalome Wetwatana and Aroua, Mohamed Kheireddine and Wohlrab, Sebastian (2024) Overview of the latest progress and prospects in the catalytic hydrogenation of carbon dioxide (CO2) to methanol in membrane reactors. International Journal of Hydrogen Energy, 77. pp. 936-957. ISSN 0360-3199

Abstract

Rising levels of carbon dioxide (CO2) emissions due to human activities exert a substantial adverse effect on the environment. The conversion of CO2 into methanol (CH3OH) through hydrogenation is a promising way to utilize this greenhouse gas, thus maintaining carbon in the cycle. In terms of sustainability, methanol is of particular interest because of its dual utilization potential as a fuel or base material to produce different chemicals. The versatility of the latter allows it to be used directly as a precursor to produce numerous compounds, including dimethyl ether (DME), olefins, formaldehydes, and hydrocarbon fuels. This paper first reviews the latest developments in catalyst design, focusing on the relationship between catalyst structure and performance. In addition, recent advances in understanding the reaction mechanisms, optimizing catalyst architectures, innovating membrane reactors, and reaction conditions have been discussed. This summarizes the strategies for increasing the efficiency of sustainable methanol production with the help of membranes. This study provides an outlook for future research in this field.