Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy.

Akyüz, S. and Akyüz, T. and Davies, D. and Eric, J. (1992) Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy. Journal of Molecular Structure, 265 (1-2). pp. 85-92.

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Abstract

The FT-IR and laser-Raman spectra of five new complexes of the formula ML2Ni(CN)4 (where M=Mn, Fe, Ni, Zn or Cd; L=3-chloropyridine) are reported. The complexes are shown to have a structure consisting of two dimensional polymeric layers formed with Ni(CN)4 ions bridged by ML2 cations. For a given series of isomorphous complexes, the effects of metal ligand bond formation on the ligand vibrational modes are examined and the metal-sensitivity sequence of the ligand frequencies is found to be Mn≈Cd<Fe<Zn<Ni.

Item Type:
Journal Article
Journal or Publication Title:
Journal of Molecular Structure
Uncontrolled Keywords:
/dk/atira/pure/researchoutput/libraryofcongress/ge
Subjects:
ID Code:
22727
Deposited By:
Deposited On:
14 Jan 2009 16:00
Refereed?:
No
Published?:
Published
Last Modified:
01 Jan 2020 06:32