Gilbert, J. S. and Bickle, M. J. and Chapman, H. J. (1994) The origin of Pyrenean Hercynian volcanic rocks (France-Spain): REE and Sm-Nd isotope constraints. Chemical Geology, 111 (1-4). pp. 207-226. ISSN 0009-2541
Full text not available from this repository.Abstract
The Hercynian orogeny of the Pyrénées generated a suite of basalt to rhyolite calc-alkaline volcanic rocks that were erupted subaerially. These melts may either have been generated above a subduction zone or by lower-crustal melting after input of mantle-derived magmas in an extensional environment. Sm---Nd garnet/whole-rock mineral isochrons date a rhyolitic ignimbrite from the Coll de Olí Ignimbrite Member at 313±14 Ma (2σ) (MSWD=0.7) and a rhyolitic lava of the Coll de Pi region at 320±2 Ma (2σ) (MSWD=0.2). These ages suggest that some of the volcanism was synchronous with high-temperature, low-pressure metamorphism and partial melting deep in the Hercynian crust as seen in rocks now exposed in the axial and northern Pyrenean zones and dated by U---Pb on zircon at between 309±5 and 315±5 Ma. The silicic volcanic rocks are peraluminous and have highly fractionated REE patterns with low abundances of the HREE and . Mineral and whole-rock REE abundances suggest derivation of the silicic rocks by partial melting of a metasedimentary source in equilibrium with garnet and/or garnet fractionation in melts derived from peraluminous sources. Nd isotope compositions of the entire volcanic rock suite (mafic-silicic compositions) are within the same range as those of sediments metamorphosed during the Hercynian orogeny and Hercynian basement rocks. They have mid-Proterozoic depleted-mantle model Sm---Nd ages and do not exhibit mixing trends with mantle sources. Even the most mafic of the volcanic rocks appear to have interacted extensively with the crust. Analysis of the chemistry of the volcanic rocks does not unequivocally constrain the Hercynian tectonic setting of the Pyrénées.