Vibrational spectroscopic investigations of M(Imidazole)2Ni(CN)4.2 Dioxane clathrates.

Tufan, Yüksel and Karacan, Nurcan and Davies, J. Eric D. (1999) Vibrational spectroscopic investigations of M(Imidazole)2Ni(CN)4.2 Dioxane clathrates. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 33 (2). pp. 149-154. ISSN 0923-0750

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Abstract

Four new clathrates of the formula M(Im)2Ni(CN)4·2·Dioxane (where M = Co, Ni, Cu, Cd; Im = Imidazole) have been prepared in powder form and their FT-IR and laser-Raman spectra are reported for the first time. These clathrates are analogues to the previously reported classical Hofmann type clathrates except for the copper clathrate. The Cu clathrate has different spectral features in comparison with its analogues due to the Jahn-Teller effect.

Item Type:
Journal Article
Journal or Publication Title:
Journal of Inclusion Phenomena and Macrocyclic Chemistry
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1600
Subjects:
?? hofmann-type clathrate - metal-imidazole complexes - dioxane inclusion compounds - ir and raman spectrageneral chemistrycondensed matter physicschemistry(all)ge environmental sciences ??
ID Code:
21766
Deposited By:
Deposited On:
05 Feb 2009 14:06
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 08:21