Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization

Leonard, Elisabeth and Akien, Geoffrey and Britten, Thomas and Kazi, Nahin and Roberts, Dean and McLaughlin, Mark (2023) Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization. Advanced Synthesis & Catalysis, 365 (22). pp. 3872-3875. ISSN 1615-4150

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Abstract

We present a rapid (0.25‐1hr), method to produce functionalised allylsilanes from readily available vinylsilanes. Employing a Brønsted acid catalysed dehydration as the key step, allylsilanes are produced in good yields (22‐98%) and, in most cases, as a single geometric isomer. Furthermore, a possible alkylation‐Cope pathway was discovered for certain substrates and attempts to optimise this are described.

Item Type:
Journal Article
Journal or Publication Title:
Advanced Synthesis & Catalysis
Subjects:
?? general chemistry ??
ID Code:
209292
Deposited By:
Deposited On:
06 Nov 2023 16:25
Refereed?:
Yes
Published?:
Published
Last Modified:
07 Aug 2024 15:05