Leonard, Elisabeth and Akien, Geoffrey and Britten, Thomas and Kazi, Nahin and Roberts, Dean and McLaughlin, Mark (2023) Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization. Advanced Synthesis & Catalysis, 365 (22). pp. 3872-3875. ISSN 1615-4150
Full text not available from this repository.Abstract
We present a rapid (0.25‐1hr), method to produce functionalised allylsilanes from readily available vinylsilanes. Employing a Brønsted acid catalysed dehydration as the key step, allylsilanes are produced in good yields (22‐98%) and, in most cases, as a single geometric isomer. Furthermore, a possible alkylation‐Cope pathway was discovered for certain substrates and attempts to optimise this are described.
Item Type:
Journal Article
Journal or Publication Title:
Advanced Synthesis & Catalysis
Subjects:
?? general chemistry ??
ID Code:
209292
Deposited By:
Deposited On:
06 Nov 2023 16:25
Refereed?:
Yes
Published?:
Published
Last Modified:
07 Aug 2024 15:05