Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes

Peng, Jingying and Docherty, Jamie H. and Dominey, Andrew P. and Thomas, Stephen P. (2017) Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes. Chemical Communications, 53 (34). pp. 4726-4729. ISSN 1359-7345

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Abstract

A bipyridiyl-oxazoline cobalt catalyst tBuBPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOtBu as the in situ activator with up to >98 : 2 branched : linear selectivity (24 examples, 45-92% isolated yield).

Item Type:
Journal Article
Journal or Publication Title:
Chemical Communications
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1500/1503
Subjects:
?? catalysiselectronic, optical and magnetic materialsceramics and compositesgeneral chemistrysurfaces, coatings and filmsmetals and alloysmaterials chemistrychemistry(all) ??
ID Code:
205248
Deposited By:
Deposited On:
26 Sep 2023 15:10
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 12:08