Anion detection driven by a surprising internal hydrogen-bonding association in a dinuclear rhenium(I) complex

Pelleteret, Diane and Fletcher, Nicholas C. and Doherty, Andrew P. (2007) Anion detection driven by a surprising internal hydrogen-bonding association in a dinuclear rhenium(I) complex. Inorganic Chemistry, 46 (11). pp. 4386-4388. ISSN 0020-1669

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Abstract

A neutral dinuclear rhenium(I) bipyridinetricarbonyl bromide complex has been investigated with a range of anions, giving a remarkable binding affinity for dihydrogenphosphate. These studies highlight that anion sensing can be achieved with structurally simple species provided that the compound adopts an unconventional conformation, through, for example, intramolecular hydrogen bonding in solution.

Item Type:
Journal Article
Journal or Publication Title:
Inorganic Chemistry
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1606
Subjects:
?? physical and theoretical chemistryinorganic chemistry ??
ID Code:
203432
Deposited By:
Deposited On:
13 Sep 2023 15:05
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 00:09