New stepwise approach to inert heterometallic triple-stranded helicates

Fletcher, Nicholas C. and Brown, Rodney T. and Doherty, Andrew P. (2006) New stepwise approach to inert heterometallic triple-stranded helicates. Inorganic Chemistry, 45 (16). pp. 6132-6134. ISSN 0020-1669

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The new tripodal fac-functionalized building block, fac-ruthenium-(II) tris-(5-hydroxymethyl-2,2′-bipyridine), has been synthesized as a single geometric isomer and used as starting point in the isolation of a kinetically inert heterometallic helicate by the stepwise inclusion of additional 2,2′-bipyridine chelating groups followed by a second metal ion. This stepwise synthetic methodology gives access to a new range of chiral nanoscale structures inaccessible by traditional self-assembly procedures.

Item Type:
Journal Article
Journal or Publication Title:
Inorganic Chemistry
Uncontrolled Keywords:
?? physical and theoretical chemistryinorganic chemistry ??
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Deposited On:
13 Sep 2023 14:30
Last Modified:
16 Jul 2024 00:09