Preparation and Synthetic Applications of Phototropone

Lowe, Jack P and Halcovitch, Nathan R and Coote, Susannah C (2023) Preparation and Synthetic Applications of Phototropone. Journal of Organic Chemistry, 88 (13). pp. 9514-9517. ISSN 0022-3263

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Abstract

An optimized multigram-scale route to phototropone (bicyclo[3.2.0]hepta-2,6-dien-7-one) is reported via the 4-π-photocyclization of tropone complexed to Lewis acid. Phototropone is a highly versatile molecular building block, and its conversion into 18 novel derivatives using standard transformations is demonstrated, allowing access to a variety of rigid bicyclic scaffolds.

Item Type:
Journal Article
Journal or Publication Title:
Journal of Organic Chemistry
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1605
Subjects:
?? organic chemistry ??
ID Code:
198394
Deposited By:
Deposited On:
14 Jul 2023 10:27
Refereed?:
Yes
Published?:
Published
Last Modified:
15 Jul 2024 23:56