A practical synthesis of 1,3-disubstituted cubane derivatives †

Kazi, Nahin and Aublette, Marine C. and Allinson, Sarah L. and Coote, Susannah C. (2023) A practical synthesis of 1,3-disubstituted cubane derivatives †. Chemical Communications, 59 (51). pp. 7971-7973. ISSN 1359-7345

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Abstract

A robust multigram-scale synthesis of 1,3-disubstituted cubanes (previously only available on milligram-scale) is reported. The approach exploits a readily available enone intermediate previously used for the synthesis of 1,4-disubstituted cubanes, by introducing a novel Wharton transposition to access useful quantities of 1,3-disubstituted cubanes for diverse applications.

Item Type:
Journal Article
Journal or Publication Title:
Chemical Communications
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2505
Subjects:
?? materials chemistrysurfaces, coatings and filmsmetals and alloysceramics and compositesgeneral chemistrycatalysiselectronic, optical and magnetic materialschemistry(all) ??
ID Code:
195618
Deposited By:
Deposited On:
09 Jun 2023 08:55
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 12:03