Exploiting trifluoromethyl substituents for tuning orbital character of singlet and triplet states to increase the rate of thermally activated delayed fluorescence

Ward, Jonathan S. and Danos, Andrew and Stachelek, Patrycja and Fox, Mark A and Batsanov, Andrei and Monkman, Andrew and Bryce, Martin (2020) Exploiting trifluoromethyl substituents for tuning orbital character of singlet and triplet states to increase the rate of thermally activated delayed fluorescence. Materials Chemistry Frontiers, 4 (12). pp. 3602-3615. ISSN 2052-1537

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Abstract

This work shows that trifluoromethyl (CF3) substituents can be used to increase the rate of thermally activated delayed fluorescence (TADF) in conjugated organic molecules by tuning the excitonic character of the singlet and triplet excited states.

Item Type:
Journal Article
Journal or Publication Title:
Materials Chemistry Frontiers
Uncontrolled Keywords:
Research Output Funding/yes_externally_funded
Subjects:
?? YES - EXTERNALLY FUNDED ??
ID Code:
193601
Deposited By:
Deposited On:
19 May 2023 14:40
Refereed?:
Yes
Published?:
Published
Last Modified:
02 Nov 2023 11:20