A homochiral 2D copper(II) coordination framework

Fielden, John and Quasdorf, Kyle and Ellern, Arkady and Kögerler, Paul (2009) A homochiral 2D copper(II) coordination framework. European Journal of Inorganic Chemistry, 2009 (6). pp. 717-720. ISSN 1434-1948

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Reaction of copper(II) salts with (S)-phenylethylaminodiacetate [(S)-peadaa] results in the 2D coordination network (S)-[Cu(peadaa)]n (space group P21), which displays an unusual Cu···Cu connectivity mode. Solid-state circular dichroism (CD) indicates a strong interaction between the ligand chiral centre and the metal centres, whereas magnetic measurements show both antiferromagnetic coupling and strong ligand field effects. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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Journal Article
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European Journal of Inorganic Chemistry
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24 Feb 2023 12:10
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15 Jul 2024 23:34