Palladacycles as precatalysts in Heck and cross-coupling reactions

Munoz-Herranz, Maria and Martín-Matute, Belén and Fernández-Rivas, Carolina and Cárdenas, Diego J. and Echavarren, Antonio M. (2001) Palladacycles as precatalysts in Heck and cross-coupling reactions. Advanced Synthesis & Catalysis, 343 (4). pp. 338-342. ISSN 1615-4150

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Abstract

A variety of palladacycles are shown to catalyze Heck alkenylations with similar efficiencies. The new oxapalladacycle 1 was shown to insert and transmetalate under mild conditions with n-butyl acrylate and vinyltributylstannane, respectively. This palladacycle acts as an active (pre)catalyst for cross-coupling and Heck reactions.

Item Type:
Journal Article
Journal or Publication Title:
Advanced Synthesis & Catalysis
Uncontrolled Keywords:
Research Output Funding/yes_externally_funded
Subjects:
?? YES - EXTERNALLY FUNDED ??
ID Code:
185745
Deposited By:
Deposited On:
03 Feb 2023 15:00
Refereed?:
Yes
Published?:
Published
Last Modified:
15 Sep 2023 01:32