Gold(I)-Catalyzed Intramolecular Cyclopropanation of Dienynes

Nieto-Oberhuber, Cristina and López, Salomé and Munoz-Herranz, Maria and Jiménez-Núñez, Eloísa and Buñuel, Elena and Cárdenas, Diego J. and Echavarren, Antonio M. (2006) Gold(I)-Catalyzed Intramolecular Cyclopropanation of Dienynes. Chemistry - A European Journal, 12 (6). pp. 1694-1702. ISSN 0947-6539

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Gold(I) complexes are the most active catalysts for the biscyclopropanation of dienynes to form tetracyclic compounds. PtII and ZnII are also able to promote the biscyclopropanation, although less efficiently. The configurations obtained in all cases with the use of gold(I) catalysts can be explained by the pathway proceeding through anti cyclopropyl gold carbenes. Similar intermediates are most probably involved in reactions catalyzed by RuII and PtII. Two different cyclopropanation pathways have been found; they depend on the structures of the cyclopropyl gold carbenes (anti or syn) and the relative arrangements of the metal carbenes and the alkenes.

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Journal Article
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Chemistry - A European Journal
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?? yes - externally fundedgeneral chemistrychemistry(all) ??
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03 Feb 2023 15:20
Last Modified:
16 Jul 2024 11:59