Recent progress in solid-state NMR of spin-½ low-γ nuclei applied to inorganic materials

Smith, Mark E. (2022) Recent progress in solid-state NMR of spin-½ low-γ nuclei applied to inorganic materials. Physical Chemistry Chemical Physics. ISSN 1463-9076

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Abstract

Significant technological and methodological advances in solid-state NMR techniques in recent years have increased the accessibility of nuclei with small magnetic moments (hereafter termed low-γ) underpinning an increased range of applications of such nuclei. These methodological advances are briefly summarised, including improvements in hardware and pulse sequences, as well as important developments in associated computational methods ( first principles calculations, spectral simulation). Here spin-½ nuclei are the focus, with this Perspective complementing a very recent review that looked at half-integer spin low-γ quadrupolar nuclei. Reference is made to some of the original reports of such spin-½ nuclei, but recent progress in the relevant methodology and applications to inorganic materials (most within the last 10 years) of these nuclei are the focus. An overview of the current state-of-the-art of studying these nuclei is thereby provided for both NMR spectroscopists and materials researchers.

Item Type:
Journal Article
Journal or Publication Title:
Physical Chemistry Chemical Physics
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1606
Subjects:
ID Code:
180845
Deposited By:
Deposited On:
09 Dec 2022 14:35
Refereed?:
Yes
Published?:
Published
Last Modified:
09 Dec 2022 14:35