Mesoporous Titania Microspheres with Highly Tunable Pores as an Anode Material for Lithium Ion Batteries

Fischer, Michael G. and Hua, Xiao and Wilts, Bodo D. and Gunkel, Ilja and Bennett, Thomas M. and Steiner, Ullrich (2017) Mesoporous Titania Microspheres with Highly Tunable Pores as an Anode Material for Lithium Ion Batteries. ACS Applied Materials and Interfaces, 9 (27). pp. 22388-22397. ISSN 1944-8244

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Abstract

Mesoporous titania microspheres (MTMs) have been employed in many applications, including (photo)catalysis as well as energy conversion and storage. Their morphology offers a hierarchical structural design motif that lends itself to being incorporated into established large-scale fabrication processes. Despite the fact that device performance hinges on the precise morphological characteristics of these materials, control over the detailed mesopore structure and the tunability of the pore size remains a challenge. Especially the accessibility of a wide range of mesopore sizes by the same synthesis method is desirable, as this would allow for a comparative study of the relationship between structural features and performance. Here, we report a method that combines sol–gel chemistry with polymer micro- and macrophase separation to synthesize porous titania spheres with diameters in the micrometer range. The as-prepared MTMs exhibit well-defined, accessible porosities with mesopore sizes adjustable by the choice of the polymers. When applied as an anode material in lithium ion batteries (LIBs), the MTMs demonstrate excellent performance. The influence of the pore size and an in situ carbon coating on charge transport and storage is examined, providing important insights for the optimization of structured titania anodes in LIBs. Our synthesis strategy presents a facile one-pot approach that can be applied to different structure-directing agents and inorganic materials, thus further extending its scope of application.

Item Type:
Journal Article
Journal or Publication Title:
ACS Applied Materials and Interfaces
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500
Subjects:
ID Code:
171431
Deposited By:
Deposited On:
07 Jun 2022 13:55
Refereed?:
Yes
Published?:
Published
Last Modified:
22 Nov 2022 11:31