Recent advances in the catalytic generation of N-Acyliminium ions and subsequent applications

Basson, Ashley and McLaughlin, Mark (2022) Recent advances in the catalytic generation of N-Acyliminium ions and subsequent applications. Tetrahedron, 114. ISSN 0040-4020

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Abstract

N-acyliminium ions are highly electrophilic reactive intermediates which allow functionalization α to an amide or carbamate. Traditionally accessed using stoichiometric quantities, catalytic generation continually offers greater control and selectivity. This review provides an overview of the most recent advancements in catalytic access to N-acyliminium ions using Brønsted acid, Lewis acid, photoredox and redox mediated pathways.

Item Type:
Journal Article
Journal or Publication Title:
Tetrahedron
Uncontrolled Keywords:
Data Sharing Template/no
Subjects:
ID Code:
168662
Deposited By:
Deposited On:
13 Apr 2022 09:45
Refereed?:
Yes
Published?:
Published
Last Modified:
22 Nov 2022 11:20