Efficient solid-state photoswitching of methoxyazobenzene in a metal–organic framework for thermal energy storage

Griffiths, Kieran and Halcovitch, Nathan and Griffin, John (2022) Efficient solid-state photoswitching of methoxyazobenzene in a metal–organic framework for thermal energy storage. Chemical Science, 13 (10). pp. 3014-3019. ISSN 2041-6520

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Abstract

4-Methoxyazobenzene can be occluded into the pores of a MOF and show near-quantitative E → Z photoisomerization under irradiation with 365 nm light. The energy density of the composite is 101 J g<jats:sup/>−1 and the half-life of the Z-isomer is 6 days.

Item Type:
Journal Article
Journal or Publication Title:
Chemical Science
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600
Subjects:
ID Code:
166599
Deposited By:
Deposited On:
01 Mar 2022 15:40
Refereed?:
Yes
Published?:
Published
Last Modified:
20 May 2022 00:35