In Situ Investigation of Expansion during the Lithiation of Pillared MXenes with Ultralarge Interlayer Distance

Maughan, Philip A. and Arnold, Stephanie and Zhang, Yuan and Presser, Volker and Tapia-Ruiz, Nuria and Bimbo, Nuno (2021) In Situ Investigation of Expansion during the Lithiation of Pillared MXenes with Ultralarge Interlayer Distance. The Journal of Physical Chemistry C, 125 (38). ISSN 1932-7447

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Abstract

Pillared Ti3C2Tz MXene with a large interlayer spacing (1.75 nm) is shown to be promising for high-power Li-ion batteries. Pillaring dramatically enhances the electrochemical performance, with superior capacities, rate capability, and cycling stability compared to the nonpillared material. In particular, at a high rate of 1 A g–1, the SiO2-pillared MXene has a capacity over 4.2 times that of the nonpillared material. For the first time, we apply in situ electrochemical dilatometry to study the volume changes within the MXenes during (de)lithiation. The pillared MXene has superior performance despite larger volume changes compared to the nonpillared material. These results give key fundamental insights into the behavior of Ti3C2Tz electrodes in organic Li electrolytes and demonstrate that MXene electrodes should be designed to maximize interlayer spacings and that MXenes can tolerate significant initial expansions. After 10 cycles, both MXenes show nearly reversible thickness changes after the charge–discharge process, explaining the stable long-term electrochemical performance.

Item Type:
Journal Article
Journal or Publication Title:
The Journal of Physical Chemistry C
Additional Information:
This document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Physical Chemistry C, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.jpcc.1c05092
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2504
Subjects:
ID Code:
160603
Deposited By:
Deposited On:
07 Oct 2021 10:50
Refereed?:
Yes
Published?:
Published
Last Modified:
19 Nov 2021 11:59