Domino Alkene-Isomerization–Claisen Rearrangement Strategy to Substituted Allylsilanes

McLaughlin, Mark and Cooke, Matthew J. (2012) Domino Alkene-Isomerization–Claisen Rearrangement Strategy to Substituted Allylsilanes. The Journal of Organic Chemistry, 77 (4). pp. 2058-2063.

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Abstract

A one-pot isomerization–Claisen protocol has been developed for the synthesis of highly substituted allylsilanes. Monosilylated divinyl ethers can be isomerized using a cationic iridium(I) catalyst followed by a thermal Claisen rearrangement to provide the allylsilanes in excellent yields and diastereoselectivities.

Item Type:
Journal Article
Journal or Publication Title:
The Journal of Organic Chemistry
ID Code:
158608
Deposited By:
Deposited On:
20 Aug 2021 13:10
Refereed?:
Yes
Published?:
Published
Last Modified:
20 Sep 2021 10:15