MIDA–Vinylsilanes:Selective Cross-Couplings and Applications to the Synthesis of Functionalized Stilbenes

McLaughlin, Mark and McAdam, C.A. and Cook, Matthew J. (2015) MIDA–Vinylsilanes:Selective Cross-Couplings and Applications to the Synthesis of Functionalized Stilbenes. Organic Letters, 17 (1). pp. 10-13. ISSN 1523-7060

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Abstract

A rapid and stereodefined synthesis of MIDA–boryl vinylsilanes has been achieved through the hydrosilylation of an alkynylboronic ester. The E products which contain a silyl and boryl group can be selectively cross-coupled in a two-step bidirectional sequence to provide a rapid and high-yielding synthesis of complex styrenes.

Item Type:
Journal Article
Journal or Publication Title:
Organic Letters
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1606
Subjects:
ID Code:
158604
Deposited By:
Deposited On:
03 Sep 2021 10:50
Refereed?:
Yes
Published?:
Published
Last Modified:
20 Sep 2021 10:15