Sustainable Access to 5‐Amino‐Oxazoles and Thiazoles via Calcium‐Catalyzed Elimination‐Cyclization with Isocyanides

Basson, Ashley J. and McLaughlin, Mark G. (2021) Sustainable Access to 5‐Amino‐Oxazoles and Thiazoles via Calcium‐Catalyzed Elimination‐Cyclization with Isocyanides. ChemSusChem, 14 (7). pp. 1696-1699. ISSN 1864-5631

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Abstract

Herein, we report a sustainable, modular, rapid and high-yielding transformation to afford densely functionalized 5-aminooxazoles and thiazoles. The reaction is tolerant to a wide range of functional groups and is typically complete in under 30 min. Furthermore, the described transformation is inherently green in relation to the catalyst and solvent choice as well as producing environmentally benign alcoholic by-products.

Item Type:
Journal Article
Journal or Publication Title:
ChemSusChem
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1500
Subjects:
ID Code:
158596
Deposited By:
Deposited On:
27 Aug 2021 15:45
Refereed?:
Yes
Published?:
Published
Last Modified:
06 Oct 2021 08:25