Aza-Peterson Olefinations:Rapid Synthesis of (E)-Alkenes

Britten, Thomas K. and Basson, Ashley J. and Roberts, Dean D. and McLaughlin, Mark G. (2021) Aza-Peterson Olefinations:Rapid Synthesis of (E)-Alkenes. SYNTHESIS. ISSN 0039-7881

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Abstract

An aza-Peterson olefination methodology to access 1,3-dienes and stilbene derivatives from the corresponding allyl- or benzyltrimethylsilane is described. Silanes can be deprotonated using Schlosser’s base and added to N-phenyl imines or ketones to directly give the desired products in high yields.

Item Type:
Journal Article
Journal or Publication Title:
SYNTHESIS
Additional Information:
Author was employed at another UK HEI at the time of submission and was deposited at Manchester Metropolitan University Repository, see link https://e-space.mmu.ac.uk/627594/
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1500/1503
Subjects:
ID Code:
158595
Deposited By:
Deposited On:
01 Sep 2021 13:40
Refereed?:
Yes
Published?:
Published
Last Modified:
06 Oct 2021 08:25