A Simple and Efficient Device and Method for Measuring the Kinetics of Gas-Producing Reactions

Slot, Thierry and Raveendran, Shiju and Rothenberg, G (2019) A Simple and Efficient Device and Method for Measuring the Kinetics of Gas-Producing Reactions. Angewandte Chemie International Edition, 58 (48). pp. 17273-17276. ISSN 1433-7851

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Abstract

We present a new device for quantifying gases or gas mixtures based on the simple principle of bubble counting. With this device, we can follow reaction kinetics down to volume step sizes of 8–12 μL. This enables the accurate determination of both time and size of these gas quanta, giving a very detailed kinetic analysis. We demonstrate this method and device using ammonia borane hydrolysis as a model reaction, obtaining Arrhenius plots with over 300 data points from a single experiment. Our device not only saves time and avoids frustration, but also offers more insight into reaction kinetics and mechanistic studies. Moreover, its simplicity and low cost open opportunities for many lab applications.

Item Type:
Journal Article
Journal or Publication Title:
Angewandte Chemie International Edition
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1500/1503
Subjects:
?? CHEMISTRY(ALL)CATALYSIS ??
ID Code:
146121
Deposited By:
Deposited On:
02 Sep 2020 15:20
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Sep 2023 02:11