Halloysite nanoclay supported adsorptive removal of oxytetracycline antibiotic from aqueous media

Ramanayaka, Sammani and Sarkar, Binoy and Cooray, Asitha T. and Ok, Yong Sik and Vithanage, Meththika (2020) Halloysite nanoclay supported adsorptive removal of oxytetracycline antibiotic from aqueous media. Journal of Hazardous Materials, 384. ISSN 0304-3894

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Abstract

Halloysite nanoclay was utilized to retain aqueous oxytetracycline (OTC) which is extensively used in the veterinary industry. The micro-structure and functionality of the nanoclay were characterized through spectroscopic techniques before and after adsorption. The OTC removal experiments were performed at different pH conditions (pH 3.0–9.0), ionic strengths (0.001, 0.01, 0.1 M NaNO3) and contact time (up to 32 h) at an initial 25 mg/L OTC concentration with 1.0 g/L halloysite. Oxytetracycline adsorption was pH dependent, and the best pH was observed in the range of pH 3.5–5.5 at a 0.001 M ionic strength. At pH 3.5, the maximum OTC adsorption amount was 21 mg/g which translated to 68% removal of the initial OTC loading. Positively charged inner lumen and negatively charged outer lumen of the tubular halloysite structure led to form inner-sphere complexes with the anionic and cationic forms of OTC, respectively. A rapid adsorption of OTC was observed in the kinetic study where 62% OTC was adsorbed in 90 min. Pseudo-second order equation obeyed by the kinetic data indicated that the adsorption was governed by chemisorption, whereas Hill isotherm equation was the most fitted with a maximum adsorption capacity of 52.4 mg/g indicating a cooperative adsorption phenomenon.

Item Type:
Journal Article
Journal or Publication Title:
Journal of Hazardous Materials
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2300/2307
Subjects:
ID Code:
140123
Deposited By:
Deposited On:
13 Jan 2020 09:20
Refereed?:
Yes
Published?:
Published
Last Modified:
24 Nov 2020 08:17