Polynuclear ampyrone based 3d coordination clusters

Sampani, Stavroula I. and Loukopoulos, Edward and Azam, Mohammad and Griffiths, Kieran and Abdul-Sada, Alaa and Tizzard, Graham and Coles, Simon and Escuer, Albert and Tsipis, Athanassios and Kostakis, George E. (2018) Polynuclear ampyrone based 3d coordination clusters. CrystEngComm, 20 (10). pp. 1411-1421. ISSN 1466-8033

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Abstract

The use of the monoanionic Schiff base ligand (E)-4-(2-hydroxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one in transition (Co, Ni and Cu) coordination chemistry yields mono-, tetra- and pentanuclear coordination clusters (CCs) with different structural motifs. An organic transformation occurs in the ligand in the Cu compound for which theoretical studies are presented. Solution studies, topological issues and magnetic studies are discussed. The present results demonstrate the richness of the coordination chemistry of this monoprotic organic ligand, which promotes the formation of high-nuclearity CCs.

Item Type:
Journal Article
Journal or Publication Title:
CrystEngComm
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/3100/3104
Subjects:
ID Code:
137066
Deposited By:
Deposited On:
01 Oct 2019 11:25
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Dec 2020 07:28