Highly efficient tetranuclear ZnII2LnIII2 catalysts for the friedel-crafts alkylation of indoles and nitrostyrenes

Kumar, Prashant and Lymperopoulou, Smaragda and Griffiths, Kieran and Sampani, Stavroula I. and Kostakis, George E. (2016) Highly efficient tetranuclear ZnII2LnIII2 catalysts for the friedel-crafts alkylation of indoles and nitrostyrenes. Catalysts, 6 (9). ISSN 2073-4344

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Abstract

We demonstrate for the first time the high efficacy of tetranuclear ZnII2LnIII2 coordination clusters (CCs) as catalysts for the Friedel-Crafts (FC) alkylation of indoles with a range of trans-β-nitrostyrenes. The reaction proceeds in good to excellent yields (76%-99%) at room temperature with catalyst loadings as low as 1.0 mol %.

Item Type:
Journal Article
Journal or Publication Title:
Catalysts
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1606
Subjects:
ID Code:
137062
Deposited By:
Deposited On:
01 Oct 2019 10:30
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Dec 2020 07:28