Tetranuclear Zn2Ln2 coordination clusters as catalysts in the Petasis borono-Mannich multicomponent reaction

Kumar, Prashant and Griffiths, Kieran and Lymperopoulou, Smaragda and Kostakis, George E. (2016) Tetranuclear Zn2Ln2 coordination clusters as catalysts in the Petasis borono-Mannich multicomponent reaction. RSC Advances, 6 (82). pp. 79180-79184. ISSN 2046-2069

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Abstract

We report herein for the first time the efficiency of heteronuclear Zn/Ln coordination clusters (CCs) as catalysts for the multicomponent Mannich-type condensation that involves amines, aldehydes and boronic acids, known as the Petasis borono-Mannich (RBR) reaction. The reaction proceeds in very good to excellent yields (84-98%, 17 products) at room temperature with catalyst loadings as low as 1.0 mol%.

Item Type:
Journal Article
Journal or Publication Title:
RSC Advances
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1500
Subjects:
ID Code:
137061
Deposited By:
Deposited On:
01 Oct 2019 10:05
Refereed?:
Yes
Published?:
Published
Last Modified:
27 Oct 2020 09:23