Heteronuclear 3 d/DyIII coordination clusters as catalysts in a domino reaction

Griffiths, Kieran and Gallop, Christopher W.D. and Abdul-Sada, Alaa and Vargas, Alfredo and Navarro, Oscar and Kostakis, George E. (2015) Heteronuclear 3 d/DyIII coordination clusters as catalysts in a domino reaction. Chemistry - A European Journal, 21 (17). pp. 6358-6361. ISSN 0947-6539

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Abstract

Three isoskeletal tetranuclear coordination clusters with general formula [MII2DyIII2L4(EtOH)6](ClO4)2·2 EtOH, (M=Co, 1; M=Ni, 2) and [NiII2DyIII2L4Cl2(CH3CN)2]·2 CH3CN (3), have been synthesized and characterized. These air-stable compounds, and in particular 3, display efficient homogeneous catalytic behavior in the room-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere.

Item Type:
Journal Article
Journal or Publication Title:
Chemistry - A European Journal
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1605
Subjects:
ID Code:
137053
Deposited By:
Deposited On:
01 Oct 2019 09:10
Refereed?:
Yes
Published?:
Published
Last Modified:
17 Jun 2020 07:30