An examination of catalyst deactivation in p-chloronitrobenzene hydrogenation over supported gold

Cardenas-Lizana, Fernando and Wang, Xiaodong and Lamey, Daniel and Li, Maoshuai and Keane, Mark A. and Kiwi-Minsker, Lioubov (2014) An examination of catalyst deactivation in p-chloronitrobenzene hydrogenation over supported gold. Chemical Engineering Journal, 255. pp. 695-704. ISSN 1385-8947

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Abstract

The stability of Au/Al2O3 in the continuous gas phase (423 K) hydrogenation of p-chloronitrobenzene (p-CNB) to p-chloroaniline (p-CAN) has been investigated over an inlet H2/p-CNB = 4–390, i.e. from close to stoichiometry to H2 far in excess. The catalyst (activated unused and spent) has been characterised with respect to specific surface area (SSA)/porosity, temperature programmed reduction (TPR), powder XRD, H2 chemisorption, STEM, XPS, elemental analysis and TGA–DSC measurements. Activation of Au/Al2O3 by TPR in hydrogen generated a narrow Au size distribution (1–8 nm, mean = 3.6 nm) with evidence (from XPS) of (support → metal) charge transfer to generate surface Auδ−. Exclusive p-CAN production was achieved under conditions of kinetic control, which were established by parameter estimation and experimental variation of contact time, catalyst particle size and p-CNB/catalyst ratio. A temporal decline in activity was observed that was more pronounced at H2/p-CNB ⩽39. The spent catalyst exhibited equivalent SSA/porosity, Au particle size (from STEM) and electronic character (from XPS) relative to activated unused Au/Al2O3. A significant carbon content (6.3% w/w) was determined from elemental analysis and confirmed by XPS and TGA–DSC. This carbon deposit hindered H2 chemisorption under reaction conditions, leading to suppressed hydrogenation activity. Catalyst regeneration by oxidative/reductive treatment resulted in a restoration of the initial hydrogenation activity, retaining exclusive selectivity to p-CAN.

Item Type:
Journal Article
Journal or Publication Title:
Chemical Engineering Journal
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2200/2209
Subjects:
ID Code:
136892
Deposited By:
Deposited On:
23 Sep 2019 10:25
Refereed?:
Yes
Published?:
Published
Last Modified:
12 Aug 2020 09:32