Hydrostannation of Acetylenic Acid Derivatives

Bew, Sean P. and Sweeney, J. B. (1991) Hydrostannation of Acetylenic Acid Derivatives. SYNLETT, 1991 (2). pp. 109-110. ISSN 0936-5214

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The reaction of acetylenedicarboxylic acid and propiolic acid with tributyltin hydride efficiently yields vinylic tin compounds bis(tributylstannyl) 2-tributylstannylbutenedioates (E/Z,1:20) and tributylstannyl 3-tributylstannylacrylates (E/Z,1:1), respectively, with regiochemistry similar to that seen in the reaction of the corresponding esters.

Item Type: Journal Article
Journal or Publication Title: SYNLETT
Uncontrolled Keywords: /dk/atira/pure/subjectarea/asjc/1600/1605
ID Code: 133271
Deposited By: ep_importer_pure
Deposited On: 30 Apr 2019 10:55
Refereed?: Yes
Published?: Published
Last Modified: 01 Jan 2020 11:59
URI: https://eprints.lancs.ac.uk/id/eprint/133271

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