Discriminant Analysis with Singular Covariance Matrices : Methods and Applications to Spectroscopic Data

Krzanowski, W. J. and Jonathan, P. and McCarthy, W. V. and Thomas, M. R. (1995) Discriminant Analysis with Singular Covariance Matrices : Methods and Applications to Spectroscopic Data. Journal of the Royal Statistical Society: Series C (Applied Statistics), 44 (1). pp. 101-115. ISSN 0035-9254

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Abstract

Currently popular techniques such as experimental spectroscopy and computer-aided molecular modelling lead to data having very many variables observed on each of relatively few individuals. A common objective is discrimination between two or more groups, but the direct application of standard discriminant methodology fails because of singularity of covariance matrices. The problem has been circumvented in the past by prior selection of a few transformed variables, using either principal component analysis or partial least squares. Although such selection ensures non-singularity of matrices, the decision process is arbitrary and valuable information on group structure may be lost. We therefore consider some ways of estimating linear discriminant functions without such prior selection. Several spectroscopic data sets are analysed with each method, and questions of bias of assessment procedures are investigated. All proposed methods seem worthy of consideration in practice.

Item Type:
Journal Article
Journal or Publication Title:
Journal of the Royal Statistical Society: Series C (Applied Statistics)
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2600/2613
Subjects:
?? statistics and probabilitystatistics, probability and uncertainty ??
ID Code:
133153
Deposited By:
Deposited On:
24 Apr 2019 12:40
Refereed?:
Yes
Published?:
Published
Last Modified:
14 Aug 2024 23:38