"Ligand-free" cluster quantized charging in an ionic liquid

Mertens, S.F.L. and Vollmer, C. and Held, A. and Aguirre, M.H. and Walter, M. and Janiak, C. and Wandlowski, T. (2011) "Ligand-free" cluster quantized charging in an ionic liquid. Angewandte Chemie International Edition, 50 (41). pp. 9735-9738. ISSN 1433-7851

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On a charge: The experimental capacitance per cluster (C) as a function of charge state (z, see picture) confirms the quantized charging of "ligand-free" metal clusters in an ionic liquid. DFT calculations indicate a switch in orientation of the ionic shell around the clusters when the sign of the charge changes, and explain the maximum capacitance at zero charge. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Angewandte Chemie International Edition
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22 Apr 2019 13:05
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22 Nov 2022 07:25