Insight into occurrence, profile and spatial distribution of organochlorine pesticides in soils of solid waste dumping sites of Pakistan : Influence of soil properties and implications for environmental fate

Sultan, Marriya and Waheed, Sidra and Ali, Usman and Sweetman, Andrew James and Jones, Kevin C. and Malik, Riffat Naseem (2019) Insight into occurrence, profile and spatial distribution of organochlorine pesticides in soils of solid waste dumping sites of Pakistan : Influence of soil properties and implications for environmental fate. Ecotoxicology and Environmental Safety, 170. pp. 195-204. ISSN 0147-6513

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Abstract

Waste dumping sites are considered as significant disposal pathway for waste contaminants including pesticides. In the present study OCPs were analyzed in soils of waste dumping sites of Pakistan. The mean concentrations of OCPs were in the order: ∑DDTs>∑HCHs>∑Endosulfan>∑HCB>Heptachlor. Order of overall ∑OCPs contamination with respect to location was Lahore>Sukkur>Karachi>Kamoki>Faisalabad>Hyderabad>Losar>Gujrat>Peshawar. Distribution of OCPs in solid waste dumping site was mainly influenced by textural classes, input history and pollution source. Soil texture was the dominant factor for retention of OCPs, whereas TOC and black carbon has not significantly impacted the concentrations of OCPs. Diagnostic ratios indicated the historical input, anaerobic degradation pathway and use of technical mixtures of DDTs in majority of waste dumping sites whereas for HCHs recent as well as past usage of technical mixture was prevalent in most of the areas. Regression analysis revealed a weak positive correlation of OCPs with socioeconomic indices (HDI, Population, waste generation) which is linked with history of use of these contaminants in the respective areas. Forecasted waste generation quantity for the year 2026 showed that waste generation amount will get doubled by the year 2026 suggesting the need properly designed waste management system.

Item Type:
Journal Article
Journal or Publication Title:
Ecotoxicology and Environmental Safety
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2300/2310
Subjects:
?? black carbonocpspopstotal organic carbonwaste dumpingδ c stable isotopepollutionpublic health, environmental and occupational healthhealth, toxicology and mutagenesis ??
ID Code:
129725
Deposited By:
Deposited On:
28 Jan 2020 16:25
Refereed?:
Yes
Published?:
Published
Last Modified:
15 Jul 2024 18:44