Catalytic C-C Bond Formation Using a Simple Nickel Precatalyst System : Base- and Activator-Free Direct C-Allylation by Alcohols and Amines

Sweeney, Joseph B. and Ball, Anthony K. and Smith, Luke J. (2018) Catalytic C-C Bond Formation Using a Simple Nickel Precatalyst System : Base- and Activator-Free Direct C-Allylation by Alcohols and Amines. Chemistry - A European Journal, 24 (29). pp. 7354-7357. ISSN 0947-6539

[thumbnail of Sweeney et al. revised Ni C-allylation]

Preview

PDF (Sweeney et al. revised Ni C-allylation)
Sweeney_et_al._revised_Ni_C_allylation.pdf - Accepted Version
Available under License Creative Commons Attribution-NonCommercial.
Download (1MB)

Abstract

A "totally catalytic" nickel(0)-mediated method for base-free direct alkylation of allyl alcohols and allyl amines is reported. The reaction is selective for monoallylation, uses an inexpensive NiII precatalyst system, and requires no activating reagents to be present.

Item Type:

Journal Article

Journal or Publication Title:

Chemistry - A European Journal

Additional Information:

This is the peer reviewed version of the following article: J. B. Sweeney, A. K. Ball, L. J. Smith, Chem. Eur. J. 2018, 24, 7354 which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/chem.201801241/abstract This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.

Uncontrolled Keywords:

/dk/atira/pure/subjectarea/asjc/1600/1600

Subjects:

?? allylationc-c bond formationnickelquaternarysustainable chemistrygeneral chemistrychemistry(all) ??

ID Code:

125113

Deposited By:

ep_importer_pure

Deposited On:

11 May 2018 15:12

Refereed?:

Yes

Published?:

Published

Last Modified:

24 Dec 2024 01:50

URI:

https://eprints.lancs.ac.uk/id/eprint/125113