A study of an azonitrile containing a sizable fluorocarbon group.

Bevington, J. C. and Guyot, B. and Huckerby, T. N. and Hunt, B. J. and Jones, R. (2000) A study of an azonitrile containing a sizable fluorocarbon group. European Polymer Journal, 36 (4). pp. 657-661. ISSN 0014-3057

Full text not available from this repository.

Abstract

The azonitrile of formula (C8F17·[CH2]2·O·CO·[CH2]2·C(CH3)(CN):N:)2 was used to initiate radical polymerizations of styrene and methyl methacrylate at 60°C. It was shown that transfer to initiator and primary radical termination can be neglected for those systems. Fluorine-containing end-groups in the resulting polymers could be easily detected by 19F-NMR, but there were some uncertainties about quantitative determinations; they may have resulted from the presence of impurities in the initiator.

Item Type:
Journal Article
Journal or Publication Title:
European Polymer Journal
Uncontrolled Keywords:
/dk/atira/pure/researchoutput/libraryofcongress/qh301
Subjects:
ID Code:
10820
Deposited By:
Deposited On:
24 Jul 2008 13:37
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Jan 2020 06:01