THE EFFECTS OF ALLYL ETHERS UPON RADICAL POLYMERIZATIONS.

Bevington, J. C. and Huckerby, T. N. and Hunt, B. J. and Jenkins, A. D. (2001) THE EFFECTS OF ALLYL ETHERS UPON RADICAL POLYMERIZATIONS. Journal of Macromolecular Science Part A Pure and Applied Chemistry, 38 (7). pp. 627-640. ISSN 1060-1325

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Abstract

Three allyl ethers, viz. the ethyl, 2-hydroxyethyl and phenyl compounds, have been examined as additives in radical polymerizations of styrene (STY), methyl methacrylate (MMA) and acrylonitrile (ACN) at 60°C using azobisisobutyronitrile as initiator. As retarders and transfer agents, the ethers are considerably more effective with ACN than with the other monomers. Allyl phenyl ether engages in significant copolymerization with ACN and slight copolymerization with MMA; there is negligible incorporation in polySTY.

Item Type:
Journal Article
Journal or Publication Title:
Journal of Macromolecular Science Part A Pure and Applied Chemistry
Uncontrolled Keywords:
/dk/atira/pure/researchoutput/libraryofcongress/qh301
Subjects:
ID Code:
10776
Deposited By:
Deposited On:
24 Jul 2008 08:47
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Jan 2020 06:01