On-off porosity switching in a molecular organic solid

Jones, James T. A. and Holden, Daniel and Mitra, Tamoghna and Hasell, Tom and Adams, Dave J. and Jelfs, Kim E. and Trewin, Abbie and Willock, David J. and Day, Graeme M. and Bacsa, John and Steiner, Alexander and Cooper, Andrew I. (2011) On-off porosity switching in a molecular organic solid. Angewandte Chemie International Edition, 50 (3). pp. 749-753. ISSN 1433-7851

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Abstract

Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.

Item Type:
Journal Article
Journal or Publication Title:
Angewandte Chemie International Edition
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1500/1503
Subjects:
?? CONFORMERSCOOPERATIVE DIFFUSIONMICROPOROUS MATERIALSMOLECULAR CAGESFRAMEWORKSSORPTIONCRYSTALCAGESCHEMISTRY(ALL)CATALYSIS ??
ID Code:
65979
Deposited By:
Deposited On:
12 Aug 2013 10:57
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Sep 2023 00:58