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Protonated open and half-open ruthenocenes exhibiting agostic interactions with C-H bond rupture involved in the most facile dynamic process

Cox, David and Roulet, Raymond (1989) Protonated open and half-open ruthenocenes exhibiting agostic interactions with C-H bond rupture involved in the most facile dynamic process. Chemical Communications (3). pp. 175-177. ISSN 1359-7345

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Abstract

The cations [Ru(η5-C7H11)2H]+(1), [Ru(η5-C5H5)(η5-C7H11)H]+(2), and [Ru(η5-C7H11)H]+(3) have provided quantitative evidence for the existence of a class of complexes in which rupture of the C–H component of a C–H–M agostic interaction is involved in the lowest energy fluxional processes.

Item Type: Article
Journal or Publication Title: Chemical Communications
Subjects:
Departments: Faculty of Science and Technology > Lancaster Environment Centre
ID Code: 64978
Deposited By: ep_importer_pure
Deposited On: 10 Jun 2013 10:28
Refereed?: Yes
Published?: Published
Last Modified: 20 Sep 2017 06:32
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/64978

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