Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’ [Ru(5-C7H11)2H]BF4

Cox, David and Roulet, Raymond (1988) Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’ [Ru(5-C7H11)2H]BF4. Chemical Communications (14). pp. 951-953. ISSN 1359-7345

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Abstract

Chloride extraction from [Ru(η3 : η3-C10H16)Cl2]2 or [Ru(η3 : η3-C10H16)Cl2L][L = P(OMe)3 or ButNC], in the presence of diolefins, results in labilisation of the 2,7-dimethyloctadienediyl ligand and provides syntheses of some new organoruthenium complexes, including the protonated ‘open metallocene’[Ru(η5-C7H11)2H][BF4].

Item Type:
Journal Article
Journal or Publication Title:
Chemical Communications
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2504
Subjects:
?? MATERIALS CHEMISTRYSURFACES, COATINGS AND FILMSMETALS AND ALLOYSCERAMICS AND COMPOSITESCHEMISTRY(ALL)CATALYSISELECTRONIC, OPTICAL AND MAGNETIC MATERIALS ??
ID Code:
64975
Deposited By:
Deposited On:
10 Jun 2013 09:27
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Sep 2023 00:55