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Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’ [Ru(5-C7H11)2H]BF4

Cox, David and Roulet, Raymond (1988) Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’ [Ru(5-C7H11)2H]BF4. Chemical Communications (14). pp. 951-953. ISSN 1359-7345

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Abstract

Chloride extraction from [Ru(η3 : η3-C10H16)Cl2]2 or [Ru(η3 : η3-C10H16)Cl2L][L = P(OMe)3 or ButNC], in the presence of diolefins, results in labilisation of the 2,7-dimethyloctadienediyl ligand and provides syntheses of some new organoruthenium complexes, including the protonated ‘open metallocene’[Ru(η5-C7H11)2H][BF4].

Item Type: Article
Journal or Publication Title: Chemical Communications
Subjects:
Departments: Faculty of Science and Technology > Lancaster Environment Centre
ID Code: 64975
Deposited By: ep_importer_pure
Deposited On: 10 Jun 2013 10:27
Refereed?: Yes
Published?: Published
Last Modified: 20 Sep 2017 06:32
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/64975

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