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The synthesis of Ru(diene)2P(OMe)3 complexes and the formation of 3:3-octadienediyl or 4-octatriene ligands upon phosphite addition to M(dimethylbutadiene)2CO (M=Fe, Ru).

Cox, David and Roulet, Raymond (1988) The synthesis of Ru(diene)2P(OMe)3 complexes and the formation of 3:3-octadienediyl or 4-octatriene ligands upon phosphite addition to M(dimethylbutadiene)2CO (M=Fe, Ru). Journal of Organometallic Chemistry, 342 (1). pp. 87-95. ISSN 0022-328X

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Abstract

Low temperature addition of P(OMe)3 to Ru/2,3-dimethylbutadiene and Ru/1,3-cyclohexadiene cocondensates yields Ru(diene)2P(OMe)3 complexes. The reactions of the bis(dimethylbutadiene) complexes M(C6H10)CO (M  Fe, Ru) with P(OMe)3 give new complexes containing either η3:η3-octadienediyl or η4-octatriene ligands.

Item Type: Article
Journal or Publication Title: Journal of Organometallic Chemistry
Subjects:
Departments: Faculty of Science and Technology > Lancaster Environment Centre
ID Code: 64974
Deposited By: ep_importer_pure
Deposited On: 10 Jun 2013 10:25
Refereed?: Yes
Published?: Published
Last Modified: 20 Sep 2017 06:32
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/64974

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