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Phase behaviour of room temperature ionic liquid solutions: an unusually large co-solvent effect in (water plus ethanol)

Najdanovic-Visak, Vesna and Esperanca, JMSS and Rebelo, LPN and da Ponte, MN and Guedes, HJR and Seddon, Kenneth R. and Szydlowski, J (2002) Phase behaviour of room temperature ionic liquid solutions: an unusually large co-solvent effect in (water plus ethanol). Physical Chemistry Chemical Physics, 4 (10). pp. 1701-1703. ISSN 1463-9076

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Abstract

A surprising mixed solvent effect, both in its magnitude and direction, has been found in the phase diagram of the ternary mixture of ([C4mim][PF6]+(water+ethanol)). For a molar ratio of 1∶1 of water to ethanol, the co-solvent effect in the near-critical demixing temperature can be as large as 80 K.

Item Type: Journal Article
Journal or Publication Title: Physical Chemistry Chemical Physics
Uncontrolled Keywords: HEXAFLUOROPHOSPHATE
Subjects:
Departments: Faculty of Science and Technology > Engineering
ID Code: 63075
Deposited By: ep_importer_pure
Deposited On: 22 Mar 2013 14:23
Refereed?: Yes
Published?: Published
Last Modified: 19 Jun 2018 03:33
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/63075

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