Syntheses and structures of iron(III) complexes of simple N-donor ligands

Cotton, Simon A. and Franckevicius, Vilius and Fawcett, John (2002) Syntheses and structures of iron(III) complexes of simple N-donor ligands. Polyhedron, 21 (20). pp. 2055-2061. ISSN 0277-5387

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Abstract

Syntheses and structures of mer-[FeCl3(pyrazole)(3)] (1), mer-[FeCl3(N-methylimidazole)(3)] (2), mer-[FeCl3(terpy)] (3) (terpy = 2,2': 6',2"-terpyridine), mer-[FeCl3(tptz)] (4) (tptz=2,4,6-tris(2-pyridyl)-1,3,5-triazine) and trans -[FeCl2(3-methylpyrazole)(4)]Cl (5) are reported. The structures demonstrate intramolecular N-H...Cl; imramolecular C-H... Cl; and intermolecular N-H...Cl interactions. Syntheses and analytical data are also reported for [FeCl3(imidazole)(4)] (6), but crystals suitable for X-ray study were not obtained. (C) 2002 Elsevier Science Ltd. All rights reserved.

Item Type:
Journal Article
Journal or Publication Title:
Polyhedron
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1604
Subjects:
?? SINGLE-CRYSTAL X-RAYSPECTRAMOLECULAR-STRUCTURECRYSTALDERIVATIVESCHLORIDE ALPHA,ALPHA'-DIIMINE SYSTEMN-DONORCRTERPYRIDYLIRON(III)MATERIALS CHEMISTRYPHYSICAL AND THEORETICAL CHEMISTRYINORGANIC CHEMISTRY ??
ID Code:
62833
Deposited By:
Deposited On:
14 Mar 2013 09:11
Refereed?:
Yes
Published?:
Published
Last Modified:
22 Sep 2023 00:19