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Synthesis of medium-ring and iodinated biaryl compounds by organocuprate oxidation

Surry, DS and Su, XB and Fox, DJ and Franckevicius, Vilius and Macdonald, SJF and Spring, DR (2005) Synthesis of medium-ring and iodinated biaryl compounds by organocuprate oxidation. Angewandte Chemie International Edition, 44 (12). pp. 1870-1873. ISSN 1433-7851

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Abstract

A biaryl banquet! Biphenyls with four ortho substituents, heteroaromatic compounds, iodinated biaryls, and medium rings containing biaryls are all readily synthesized by organocuprate oxidation. The utility of this new methodology is illustrated by the efficient synthesis of the medium-ring core of sanguiin H-5 (see scheme).

Item Type: Journal Article
Journal or Publication Title: Angewandte Chemie International Edition
Uncontrolled Keywords: organocuprates ; C-C coupling ; oxidation ; VINYL CHLORIDES ; TEMPLATE ; biaryls ; medium-ring compounds ; ULLMANN COUPLING REACTION ; ARYL BOND FORMATION ; 1ST SYNTHESIS ; FUNCTIONALIZED ARYLMAGNESIUM ; CONVENIENT ; SYMMETRICAL BIARYLS ; FACILE SYNTHESIS ; SALICYL ALCOHOL
Subjects:
Departments:
ID Code: 62829
Deposited By: ep_importer_pure
Deposited On: 15 Mar 2013 16:47
Refereed?: Yes
Published?: Published
Last Modified: 11 Apr 2018 00:54
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/62829

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