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Kinetic study on 2-methyl-1-butanol dehydration catalysed by ion exchange resin

Aiouache, Farid and Goto, Shigeo (2002) Kinetic study on 2-methyl-1-butanol dehydration catalysed by ion exchange resin. Journal of Chemical Engineering of Japan, 35 (5). pp. 436-442. ISSN 0021-9592

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Abstract

The dehydration of 2-methyl 1-butanol (2M1BOH) in the liquid phase was studied by using an ion-exchange resin, Amberlyst 15 in the H+ form. Experiments were carried out in a batch reactor with the dry resin as a catalyst. Considering the inhibition effect of water, the rate expressions based on the Langmuir-Hinshelwood model were formulated. The sorption equilibrium model between liquid and resin phases during resin swelling was included in kinetic modelling. The cross-linked ion-exchange resin was highly selective to water at the beginning of the reaction. The experimental results agreed well with the calculated ones.

Item Type: Article
Journal or Publication Title: Journal of Chemical Engineering of Japan
Subjects:
Departments: Faculty of Science and Technology > Engineering
ID Code: 60668
Deposited By: ep_importer_pure
Deposited On: 03 Jan 2013 11:15
Refereed?: Yes
Published?: Published
Last Modified: 17 Nov 2017 11:15
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/60668

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