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Hydrogen content estimation of hydrogenated amorphous carbon by visible Raman spectroscopy

Adamopoulos, George and Godet, Christian and Robertson, John and Morrison, Neil (2004) Hydrogen content estimation of hydrogenated amorphous carbon by visible Raman spectroscopy. Journal of Applied Physics, 96 (11). pp. 6348-6352. ISSN 0021-8979

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Abstract

In the present study, we report the hydrogen content estimation of the hydrogenated amorphous carbon (a-C:H) films using visible Raman spectroscopy in a fast and nondestructive way. Hydrogenated diamondlike carbon films were deposited by the plasma enhanced chemical vapor deposition, plasma beam source, and integrated distributed electron cyclotron resonance techniques. Methane and acetylene were used as source gases resulting in different hydrogen content and sp(2)/sp(3) fraction. Ultraviolet-visible (UV-Vis) spectroscopic ellipsometry (1.5-5 eV) as well as UV-Vis spectroscopy were provided with the optical band gap (Tauc gap). The sp(2)/sp(3) fraction and the hydrogen content were independently estimated by electron energy loss spectroscopy and elastic recoil detection analysis-Rutherford back scattering, respectively. The Raman spectra that were acquired in the visible region using the 488 nm line shows the superposition of Raman features on a photoluminescence (PL) background. The direct relationship of the sp(2) content and the optical band gap has been confirmed. The difference in the PL background for samples of the same optical band gap (sp(2) content) and different hydrogen content was demonstrated and an empirical relationship between the visible Raman spectra PL background slope and the corresponding hydrogen content was extracted.

Item Type: Article
Journal or Publication Title: Journal of Applied Physics
Subjects: T Technology > TA Engineering (General). Civil engineering (General)
Departments: Faculty of Science and Technology > Engineering
ID Code: 58571
Deposited By: ep_importer_pure
Deposited On: 29 Oct 2012 16:34
Refereed?: Yes
Published?: Published
Last Modified: 10 Apr 2014 00:11
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/58571

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