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Structural changes to epitaxial (0001) holmium layers during hydrogen loading

Grier, E. J. and Kolosov, Oleg and Petford-Long, A. K. and Ward, R. C. C. and Wells, M. R. and Hjorvarsson, B. (2000) Structural changes to epitaxial (0001) holmium layers during hydrogen loading. Journal of Physics D-Applied Physics, 33 (8). pp. 894-900. ISSN 0022-3727

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Abstract

HoHy exhibits dramatic changes in both structural and optical properties as y is varied from zero to three by hydrogen loading. This work reports on the effect of such loading upon epitaxial single-crystal Ho films grown by molecular beam epitaxy on (110) Nb parallel to(11(2) over bar 0) Al2O3 substrates. Upon loading, the film undergoes a structural transition from hcp metal (alpha-phase, H in solid solution) to the fee dihydride (beta-phase). There is a further transformation between the dihydride phase and the hexagonal trihydride (gamma-phase). Three films of HoHy, where, nominally, y = 0, 2, 3, were studied by XRD, AFM, UFM, SEM and TEM. Triangular networks of features of width similar to 300 nm and height similar to 20-30 nm that align with the [0(1) over bar 1], [(1) over bar 01] and [1(1) over bar 0] directions of the dihydride sample are seen on the surface of both the dihydride and the trihydride samples, but have a much greater density on the surface of the latter Such features are not present on the as-grown metal layer. In situ controlled-environment transmission electron microscopy (CETEM) studied the effects of hydrogen loading within the dihydride phase, in cross sectional geometry. During loading, slip within the dihydride phase was observed. The hypothesis that the triangular features are due to the precipitation of the di- and trihydride compounds, with expanded lattices, on the slip planes within the alpha- or beta-phase host crystal is discussed.

Item Type: Article
Journal or Publication Title: Journal of Physics D-Applied Physics
Subjects: Q Science > QC Physics
Departments: Faculty of Science and Technology > Physics
ID Code: 57442
Deposited By: ep_importer_pure
Deposited On: 09 Oct 2012 10:18
Refereed?: Yes
Published?: Published
Last Modified: 10 Apr 2014 00:01
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/57442

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