Akyüz, S. and Akyüz, T. and Davies, D. and Eric, J. (1992) Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy. Journal of Molecular Structure, 265 (1-2). pp. 85-92.
Full text not available from this repository.Abstract
The FT-IR and laser-Raman spectra of five new complexes of the formula ML2Ni(CN)4 (where M=Mn, Fe, Ni, Zn or Cd; L=3-chloropyridine) are reported. The complexes are shown to have a structure consisting of two dimensional polymeric layers formed with Ni(CN)4 ions bridged by ML2 cations. For a given series of isomorphous complexes, the effects of metal ligand bond formation on the ligand vibrational modes are examined and the metal-sensitivity sequence of the ligand frequencies is found to be Mn≈Cd<Fe<Zn<Ni.
| Item Type: | Article |
|---|---|
| Journal or Publication Title: | Journal of Molecular Structure |
| Subjects: | G Geography. Anthropology. Recreation > GE Environmental Sciences |
| Departments: | UNSPECIFIED |
| ID Code: | 22727 |
| Deposited By: | ep_ss_importer |
| Deposited On: | 14 Jan 2009 16:00 |
| Refereed?: | No |
| Published?: | Published |
| Last Modified: | 26 Jul 2012 16:05 |
| Identification Number: | |
| URI: | http://eprints.lancs.ac.uk/id/eprint/22727 |
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