Akyüz, S. and Akyüz, T. and Davies, D. and Eric, J. (1992) Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy. Journal of Molecular Structure, 265 (1-2). pp. 85-92.Full text not available from this repository.
The FT-IR and laser-Raman spectra of five new complexes of the formula ML2Ni(CN)4 (where M=Mn, Fe, Ni, Zn or Cd; L=3-chloropyridine) are reported. The complexes are shown to have a structure consisting of two dimensional polymeric layers formed with Ni(CN)4 ions bridged by ML2 cations. For a given series of isomorphous complexes, the effects of metal ligand bond formation on the ligand vibrational modes are examined and the metal-sensitivity sequence of the ligand frequencies is found to be Mn≈Cd<Fe<Zn<Ni.
|Journal or Publication Title:||Journal of Molecular Structure|
|Subjects:||G Geography. Anthropology. Recreation > GE Environmental Sciences|
|Deposited On:||14 Jan 2009 16:00|
|Last Modified:||07 Jan 2015 13:42|
Actions (login required)