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Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy.

Akyüz, S. and Akyüz, T. and Davies, D. and Eric, J. (1992) Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy. Journal of Molecular Structure, 265 (1-2). pp. 85-92.

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Abstract

The FT-IR and laser-Raman spectra of five new complexes of the formula ML2Ni(CN)4 (where M=Mn, Fe, Ni, Zn or Cd; L=3-chloropyridine) are reported. The complexes are shown to have a structure consisting of two dimensional polymeric layers formed with Ni(CN)4 ions bridged by ML2 cations. For a given series of isomorphous complexes, the effects of metal ligand bond formation on the ligand vibrational modes are examined and the metal-sensitivity sequence of the ligand frequencies is found to be Mn≈Cd<Fe<Zn<Ni.

Item Type: Article
Journal or Publication Title: Journal of Molecular Structure
Subjects: G Geography. Anthropology. Recreation > GE Environmental Sciences
Departments: UNSPECIFIED
ID Code: 22727
Deposited By: ep_ss_importer
Deposited On: 14 Jan 2009 16:00
Refereed?: No
Published?: Published
Last Modified: 26 Jul 2012 16:05
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/22727

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